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MONEL 400 Alloy (UNS N04400)

MONEL nickel alloy is a solid solution alloy that can be hardened by the process of cold working.
MONEL is a trademark of Special Metals Corporation under which a series of nickel-copper alloys are grouped.
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MONEL nickel alloy is a solid solution alloy that can be hardened by the process of cold working.

MONEL is a trademark of Special Metals Corporation under which a series of nickel-copper alloys are grouped.


Commercially there are many types of MONEL available, such as alloy 400, alloy 401, alloy R-405, Alloy K-500 and Monel 404.


The Monel 400 alloy is also known as super alloy monel.    This alloy is available in some standard shapes such as hexagon, round, tube, pipe, plate, strip, sheet and wire.


The proportions of copper and nickel used to make monel are the same as that found in the nickel ore found in Ontario mines. This alloy exhibits good corrosion resistance.


Chemical Composition

The chemical composition of MONEL 400 alloy is given in the following table.


Physical Properties

Element

Content (%)

Nickel, Ni

Remainder

Copper, Cu

28-34

Iron, Fe

2.5 max

Manganese, Mn

2 max

Silicon, Si

0.5 max

Carbon, C

0.3 max

Sulphur, S

0.024


The following table discusses the physical properties of MONEL 400 alloy.

Properties

Metric

Imperial

Density

8.8 gm/cm3

0.318 lb/in3


Mechanical Properties

The mechanical properties of MONEL 400 alloy are tabulated below.

Properties

Metric

Imperial

Tensile strength(annealed)

517-620 MPa

75-90 ksi

Yield strength

172-345 MPa

25-50 ksi

Modulus of elasticity

179 GPa

26000 ksi

Poisson’s ratio

0.32

0.32


Some of the other designations that are used to denote MONEL 400 alloy are as below:

AMS 4574

AMS 4675

AMS 4731

ASTM B163

ASTM B165

ASTM F96

UNS N04400


Fabrication

Machinability

The machinability of MONEL 400 is difficult as it work-hardens during machining. The conventional machining techniques used on iron alloys may be used for this alloy.

 

Welding

Welding methods including gas-arc welding, metal-arc welding, gas-metal-arc welding and submerged-arc welding are recommended on this alloy.

 

Forging

Forging of this alloy is to be done by controlled procedures.

 

Hot working

Hot working on this alloy needs to be done by choosing proper temperatures. Typical temperatures for hot working range between 648-1176°C (1200-2150°F).

 

Cold working

Cold working may be done using soft die materials for better finishing.

 

Annealing

MONEL 400 alloy may be annealed at 926°C (1700°F).

 

Applications

The MONEL 400 alloy is used in the following applications:

Marine fixtures, pumps, valves and piping systems for sea water applications

Chemical plant equipment

Frames for eyeglasses

Aerospace applications

Musical instruments.


Applications

Feed water and steam generator tubing.

Brine heaters, sea water scrubbers in tanker inert gas systems.

Sulfuric acid and hydrofluoric acid alkylation plants.

Pickling bat heating coils.

Heat exchangers in a variety of industries.

Transfer piping from oil refinery crude columns.

Plant for the refining of uranium and isotope separation in the production of nuclear fuel.

Pumps and valves used in the manufacture of perchlorethylene, chlorinated plastics.

Monoethanolamine (MEA) reboiling tube.

Cladding for the upper areas of oil refinery crude columns.

Propeller and pump shafts.


MONEL 400 Alloy (UNS N04400)


Overview

Monel 400 is a Nickel-Copper alloy, resistant to sea water and steam at high temperatures as well as to salt and caustic solutions.

Monel 400 is a nickel-copper alloy with excellent corrosion resistance in a wide variety of media. Monel 400 is characterized by good general corrosion resistance, good weldability and moderate to high strength. The alloy has been used in a variety of applications. It has excellent resistance to rapidly flowing brackish water or seawater. It is particularly resistant to hydrochloric and hydrofluoric acids when they are de-aerated. The alloy is slightly magnetic at room temperature. Monel 400 is widely used in the chemical, oil and marine industries.

 

Characteristics

Corrosion resistance in an extensive range of marine and chemical environments. From pure water to nonoxidizing mineral acids, salts and alkalis.

This alloy is more resistant to nickel under reducing conditions and more resistant than copper under oxidizing conditions, it does show however better resistance to reducing media than oxidizing.

Good mechanical properties from subzero temperatures up to about 480C.

Good resistance to sulfuric and hydrofluoric acids. Aeration however will result in increased corrosion rates. May be used to handle hydrochloric acid, but the presence of oxidizing salts will greatly accelerate corrosive attack.

Resistance to neutral, alkaline and acid salts is shown, but poor resistance is found with oxidizing acid salts such as ferric chloride.

Excellent resistance to chloride ion stress corrosion cracking.


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